Add the additional fields(better under Common Additional-Fields) as mentioned in the below link:
http://www.manageengine.com/products/service-desk/help/adminguide/configurations/user-management/configuring-user-defined-fields.html
and map it to the AD field like mentioned on the below link:
http://www.manageengine.com/products/service-desk/help/adminguide/configurations/user-management/configuring-active-directory-authentication.html
Maljeev
SDP Support - FAQ
ServiceDesk Plus - Help Desk Software of your Choice
http://www.manageengine.com/products/service-desk/help/adminguide/configurations/user-management/configuring-user-defined-fields.html
and map it to the AD field like mentioned on the below link:
http://www.manageengine.com/products/service-desk/help/adminguide/configurations/user-management/configuring-active-directory-authentication.html
Maljeev
SDP Support - FAQ
ServiceDesk Plus - Help Desk Software of your Choice